Inorganic Reaction Mechanisms

Contents

1. Inorganic Reaction Mechanisms

Kinetic Aspects of Complexes, Trans Effect, Mechanism of Substitution Reactions in Square-Planar Complexes, Electron-Transfer Reactions or Redox Reactions, Complementary Redox Reactions, Isomerisation of Octahedral Complexes, Racemisation of Octahedral Complexes.

2. Chelates and Redox Potential

Definition of Chelates, Limitations of Chelates Definition, Characteristics of Chelates, Origin of the Word Chelate, Distinction Between Metal Chelates and Metal Complexes, Chelate Ring Forming Groups, Classification of Chelates, Factors Influencing the Stability of Metal Chelates, Detection of Chelates, Importance of Chelates, Introduction to Redox Potential, Nernst’s Equation, Normal Hydrogen Gas Electrode, Electrochemical Series, EMF Diagram, Periodic Trends in EMF Values, Introduction to Borazzole, Methods of Preparation of Borazine, Properties of Borazine, Structure of Borazine, Substituted Borazine, Interhalogen Compounds, Classification of Interhalogen Compounds, Naming of Interhalogen Compounds, Causes for the Formation of Interhalogen Compounds, Exceptions to the Formation of higher Interhalogens, General Methods of Preparation of Interhalogens, Chemical Properties of Interhalogens, General Properties of Interhalogens, Compounds of the AX Type, interhalogens of the Type AX,, Interhalogens of the Type AX,, Interhalogens of the Type AX Applications of Interhalogen Compounds, Structures Nd Shapes of the Compounds AX, Structure and Shape of AB, Type Interhalogen Molecules, Structure AD Shape of AB, Type Interhalogen Molecules, Structure and Shape of CLF, Molecule, Structure and Shape of LF.

3. Peroxides, Peracides and Their Salts

Peroxides, Hydroperoxide, Peracids and Their Salts.

4. Pseudo Halogens, Halogen-Halogenoids, Polyhalides and Basic Properties of Iodine

Pseudohalogens, the Similarities Between Psuedohalogens and the Halogens, Dissimilarity Between Halogens and Pseudohalogens, Similarities Between Halide Ions and Pseudohalide Ions, Dissimilarities Between Halide Ions and Pseudohaide Ions, Free Pseudohalogens, Halogen-Halogenoids, Thiocyanogen Halides and Oxycyanogen Halides, Interhalogenoids, Polyhalides, Basic Properties of Iodine.

5. Organometallic Compounds

Introduction, Classification, Nature of Carbon Metal Bond, Methods of Preparation, Scheme I, Formation by Substitution Methods, Miscellaneous Methods, Properties of Organometallic Compounds, Cyc!o Pentadienyl Complexes, Structure, Ferrocene, FE (C,H,),, Preparation, Properties, Arene Transition Metal Complexes, Structure and Bonding, Organometallic Compounds of Lithium, Tellurium, Occurrence, Extraction, Preparation or Tellurium, Properties of Tellurium, Uses of Tellurium, Compounds of Tellruium, Halogen Compounds of Tellurium, Some Redox Titrants, Applications of Bromate in Titrimetric Analysis, Potassium Iodate, Dye Stuffs and Indicators, Preparation of 0.1N Potassium Iodate, Vanadates, Analysis Involving Vanadate Solution, Ceric Salts, Standardisation of Ceric Solution, Applications, Titanous Salts, Preparation of Titanous Solutions, Chromous Salts, Chloramine-T.